Unfolding the structural features of NASICON materials for sodium?ion full cells

Sodium-ion batteries (SIBs) are potential candidates for the replacement of lithium-ion to meet increasing demands electrical storage systems due low cost and high abundance sodium. Sodium superionic conductor (NASICON) structured materials have attracted enormous interest in recent years as electrode safer long-term performance SIBs electric energy smart grids. These a three-dimensional robust framework, redox potential, thermal stability, fast Na+-ion diffusion mechanism. However, NASICON has intrinsic electronic conductivity, which limits electrochemical performance. This review describes structural features NASICONs illustrate ion mechanism SIBs. Details crystal structure, affiliated mechanism, morphology, these sodium-ion half-cells well full cells described. In addition application materials, use solid electrolytes is also elaborated solid-state Based on aspects, we provided more perspectives terms commercialization strategies overcome limitations NASICONs. Hence, this expected provide researchers with an in-depth understanding knowledge features, will new avenue practicality